Substituent effects on homolytic versus heterolytic photocleavage of (1-naphthylmethyl)trimethylammonium chlorides
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چکیده
منابع مشابه
Homolytic versus heterolytic dissociation of alkalimetal halides: the effect of microsolvation.
Herein we report density functional calculations of homolytic and heterolytic dissociation energies of the diatomic alkalimetal halides MX (M=Li, Na, K, Rb, and Cs and X=F, Cl, Br, I, and At) and their corresponding microsolvated structures MX(H(2)O)(n) (n=1 to 4). Our results show that the homolytic dissociation energy of the MX(H(2)O)(n) species increases with the number of water molecules in...
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two groups of students were assigned as experimental and control ones, and were given instruction on directed reading-thinking activities and after some treatment, they were post-tested. although the initial pre-test did not show any significant differences, the final post-test result revealed that the cooperative reading comprehension helped the experimental group. the cooperative students’...
15 صفحه اولSubstituent effects on the nitrogen-15 and carbon-13 shieldings of some N-arylguanidinium chlorides.
The (13)C and (15)N chemical shifts of five N-arylguanidinium chlorides carrying polar substituents, ranging in character from 4-methoxy to 4-nitro groups, have been determined by NMR spectroscopy at the natural-abundance level of (13)C and (15)N in dimethyl sulfoxide solution. Comparison of the (13)C shifts of these salts with those of monosubstituted benzenes shows that the guanidinium group ...
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Two pathways are recognized for the activation of dihydrogen by metal catalysts, homolytic and heterolytic. Homolytic activation involves oxidative addition to metals usually in low oxidation states. Heterolytic activation, which occurs with no formal change in oxidation state, is associated with metals in higher oxidation states and gives rise to hydridic (H-, usually attached to a metal) and ...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1987
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v87-268